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| Peculiarities of methane
hydrate decomposition in sediments
E.M. Chuvilin1, E.V. Kozlova1, E.V.
Perlova2
1Dept. of Geocryology, Geological Faculty, Moscow State
University, Russia
2Gazprom, VNIIGAZ, Russia
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Many data about methane hydrate presence in submarine
and permafrost areas are received in during the last decades.
It is significant that often gas hydrates don¨t form bands, but
situate in a porous space of dispersed sediments as porous cement
similarly to ice-cement. As investigations shown, a gas content
of these sediments may be enough considerable. In this connection,
they can be regard as a source of a gas production.
It is necessary to know the thermodynamic conditions of gas
hydrates decomposition in a porous space for technological problems
solving.
Authors in a special pressure chamber have conducted physical
simulation of hydrate decomposition processes in dispersed sediments.
This allows influence of internal (sediments) and external (thermodynamic)
factors on the P/T parameters of hydrate intensive decomposition
in dispersed sediments to be estimated.
The analysis of the experimental data have shown an obvious
shift of the P/T conditions of a hydrate intensive decomposition
in the sediment porous space to the field of higher pressures
and lower temperatures when compared to the system "water
(ice) - free gas - gas hydrate" (P/Tg-w). This shift is not
constant and it is growing with rise of the environment temperature.
Experimental results show that sediments grain size, mineral
composition and salinity influence on the shift of the P/T conditions
of the hydrate decomposition.
The researchers have been conducted both monomineral sediments
(quartz sand, kaolinite and montmorillonite clays) and natural
polymineral silt-sand-loamy composition sediments. Natural sediments
were picked out of upper layers of permafrost where indications
of hydrate content were fixed.
The experiments, which have been conducted on the model sediments
show that the values of these shifts increase with growth of clay
particles content and salinity and with change in the soil mineral
composition following a trend from kaolinite clay to montmorillonite
clay. It could be attributed to energy change of a porous water
of sediments
The experiments which have been conducted on the natural sediments
with natural humidity and salinity shown that the shift value
of the P/T conditions of the methane hydrate intensive decomposition
to average 1.6oC and 1 MPa in temperatures and pressure scales,
accordingly.
These received data point necessity of the account of the sediments
factor at estimation of natural gas hydrate decomposition in porous
space of dispersed sediments.
The research presented in this paper has been partly funded
by program of Russian Foundation for Basic Research ″ 01-05-64653.
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